Oxosorbicillinol
WebOct 20, 2024 · This hypothetical compound has the same empiric formula as oxosorbicillinol and epoxysorbicillinol, and might be compound F_265 (Table 2) that was detected in all sorbicillinoid producing strains (Figure 5). Its higher levels in Δsor4 could be explained by a feedback of the accumulating dihydrosorbicillinol on Sor1. WebOxosorbicillinol C14H16O5 CID 10015650 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities ...
Oxosorbicillinol
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WebAbe N, Yamamoto K, Hirota A: Novel fungal metabolites, demethylsorbicillin and oxosorbicillinol, isolated from Trichoderma sp. USF-2690. Biosci Biotechnol Biochem. 2000 Mar;64(3):620-2. doi: 10.1271/bbb.64.620. [PubMed:10803967 ] Maskey RP, Grun-Wollny I, Laatsch H: Sorbicillin analogues and related dimeric compounds from … WebSorbicillinoids are a class of fungal metabolites with a cyclic hexaketide nucleus, which contains a typical or modified sorbyl sidechain [1,2].Since the isolation of the first member of the sorbicillinoid family 60 years ago (sorbicillin, from the fungus Penicillium notatum) [], approximately 100 sorbicillin derivatives have been reported from several strains of fungi …
WebOxacillin is a penicillinase-resistant β-lactam. It is similar to methicillin, and has replaced methicillin in clinical use. Other related compounds are nafcillin, cloxacillin, dicloxacillin, … WebMay 28, 2010 · Moreover, Abe [11] proved OH-4a was cis to CH 3 -1a, based on the elucidation of the biosynthesis of bisvertinolone from oxosorbicillinol and sorbicillinol. But judging from molecular models we ...
WebBiosynthetic incorporation of labeled sodium acetate into oxosorbicillinol in Trichoderma sp. USF-2690 suggests that oxosorbicillinol is derived from six acetate units, and … WebAug 23, 2024 · Language links are at the top of the page across from the title.
WebA new lipoxygenase inhibitor, 6'-hydroxyoxosorbicillinol (1, C(14) H(16)O(6)), was identified from a culture of Penicillium sp. A known compound, oxosorbicillinol (2, C(14)H(16)O(5)), was also isolated. Compound 1 showed an approximately 10 times greater inhibitory effect on soybean lipoxygenase (IC …
WebJun 1, 2016 · Molecules 2016, 21, 715 3 of 19 Table 1. Occurrence of the monomeric sorbicillinoids (1–30) in fungi.Sorbicillinoid Fungus and its Origin Ref. Sorbicillinol (1) Trichoderma sp. USF-2690 from a soil sample [14]Epoxysorbicillinol (2) Trichoderma longibrachiatum from the sponge Haliclona sp. [20]Oxosorbicillinol (3)Penicillium … is scorpion pepper hotter than a ghost pepperWebJan 13, 2024 · In contrast to prior reports, SorD catalyses neither the oxidation of 2′,3′-dihydrosorbicillin to sorbicillin nor the oxidation of sorbicillinol to oxosorbicillinol. This is the first report that both the intermolecular Diels–Alder and Michael dimerization reactions, as well as the epoxidation of sorbicillinol are catalysed in vivo by SorD. is scorpion the strongest characterWebFeb 1, 2009 · Biosynthetic incorporation of labeled sodium acetate into oxosorbicillinol in Trichoderma sp. USF-2690 suggests that oxosorbicillinol is derived from six acetate units, and subsequent bioconversion … Expand. 20. Save. Alert. Studies towards Trichodimerol: Novel Cascade Reactions and Polycyclic Frameworks. idman repackWebThe flavin-dependent monooxygenase SorD from Penicillium chrysogenum (PcSorD) utilizes sorbicillinol to catalyze a broad scope of reactions: formation of oxosorbicillinol and … is scorpion tv show canceledWebJan 1, 2000 · Abstract. The novel compounds, demethylsorbicillin (1) and oxosorbicillinol (2), were isolated from a fermentation broth of Trichoderma sp. USF-2690. The structures of these compounds, which were determined from spectroscopic evidence, suggest the possibility that methylation at C-6 and oxidation at C-1 and C-6 of sorbicillin were … is scorpion\u0027sWebJan 13, 2024 · In contrast to prior reports, SorD catalyses neither the oxidation of 2′,3′-dihydrosorbicillin to sorbicillin nor the oxidation of sorbicillinol to oxosorbicillinol. This is … is scorpion venom edibleWebMay 23, 2024 · A stable tautomer of oxosorbicillinol (7) was characterized as 6, and the recently described 7-deacetoxyyanuthone (8) was reisolated. The additionally isolated rezishanones A-D (12-13c) are the ... idman python